shaped abrasive particles, methods of preparing said particles, abrasive articles including the same

专利摘要:
CONFORMED ABRASIVE PARTICLES, METHODS OF PREPARATION, AND ABRASIVE ARTICLES INCLUDING THEM. A method of preparing abrasive particles includes: providing a slurry comprising non-colloidal solid particles and a liquid carrier; forming at least a portion of the slurry into shaped bodies that come into contact with a substrate; at least partially drying the shaped bodies to provide shaped abrasive precursor particles; separating at least a portion of the shaped abrasive precursor particles from the substrate; and converting at least a portion of the shaped abrasive precursor particles to shaped abrasive particles. The shaped abrasive particles comprise alpha alumina having an average crystal grain size of 0.8 to 8 microns and a bulk density that is at least 92 percent of true density. Each shaped abrasive particle has a respective surface comprising a plurality of smooth sides that form at least four corners. Shaped abrasive particles, abrasive articles including the same, and methods of use are also disclosed.
公开号:BR112015009886B1
申请号:R112015009886-0
申请日:2013-10-17
公开日:2021-06-08
发明作者:Anatoly Z. Rosenflanz；Negus B. Adefris
申请人:3M Innovative Properties Company；
IPC主号:

专利说明:

Field
[001] The present disclosure relates, in general, to alumina-based abrasive particles, methods of preparing the same and abrasive articles including the same. Background
[002]Alumina (ie, Al2O3), is one of the most important abrasive minerals known to the abrasive industry due to its cost balance, good thermal conductivity, strength, hardness, and chemical inertness leading to excellent grinding characteristics. in coated and bonded abrasives. It has long been known that microstructural refinement leads to improvements in abrasive characteristics. In this way, superior alumina grains produced through a chemical sol-gel route and producing fully dense sintered structures with excessively fine microstructures (<0.5 microns) were developed (eg see US patent 4,314,827 (Leitheiser et al.) and introduced into the abrasive market.The introduction of shaped abrasive particles formed from sol-gel derived alpha alumina has revolutionized the abrasive industry.These abrasive particles typically outperform corresponding crushed particles made of the same material in abrasive applications. However, these solgel-derived abrasive particles can only be obtained in sizes smaller than about 20 mesh mesh (US mesh size) Attempts to produce larger abrasive particles using the sol-gel technique are generally not successful because to cracking associated with the need to remove the large amount of volatile material during drying.
[003] Thus, it is desirable to provide powder-derived alumina abrasives without limitations on grain dimensions and with similar grinding characteristics even better than those of a sol-gel grain. Although powder-derived Al2O3 abrasives are also available (eg as a CCC grain available from Treibacher Schleifmittel AG, Villach, Austria or as sintered alumina available from ShowaDenko KK, Tokyo, Japan), their utility has been limited due to coarse microstructures that usually accompany the powder sintering method.
[004] The mechanical properties of alpha alumina are often influenced by the presence of impurities. In particular, it is widely known that impurities such as sodium have detrimental effects on the formation of alpha alumina from alumina precursors. For example, the presence of sodium oxide causes an increase in the alpha alumina crystal grain size after sintering, resulting in decreased hardness and/or fracture during the sintering process. Currently, it is believed that in the abrasive industry the thickening of microstructures significantly above the grain size range of alpha alumina crystals of about 1-2 microns is not practical for use on abrasive particles for use in precision grinding applications and coated abrasives.
[005] Consequently, high purity alpha alumina precursors are commercially used in the production of shaped alpha alumina abrasive particles. These precursors are correspondingly expensive. summary
[006] In one aspect, the present disclosure provides a method of preparing abrasive particles, the method comprising: providing a slurry comprising non-colloidal solid particles and a liquid carrier, at least some of the non-colloidal solid particles comprising at least one of alpha alumina or an alpha alumina precursor, and the non-colloidal solid particles comprising at least 30 percent by volume of the slurry; forming at least a portion of the slurry into shaped bodies which come into contact with a substrate, the shaped bodies being formed substantially in accordance with a predetermined shape; at least partially drying the shaped bodies to provide shaped abrasive precursor particles; separating at least a portion of the shaped abrasive precursor particles from the substrate; and converting at least a portion of the shaped abrasive precursor particles to shaped abrasive particles, the shaped abrasive particles comprising alpha alumina, the alpha alumina having an average crystal grain size of 0.8 to 8 microns, wherein the alpha alumina has a bulk density that is at least 92 percent of the true density, and wherein each of the shaped abrasive particles has a respective surface comprising a plurality of sides and at least four vertices, and wherein the shaped abrasive particles meet adapt to a predetermined nominal format.
[007] In another aspect, the present disclosure provides shaped abrasive particles produced according to the above method.
[008] In yet another aspect, the present disclosure provides shaped abrasive particles comprising alpha alumina, alpha alumina having an average crystal grain size of 0.8 to 8 microns, alpha alumina having a bulk density which is at least 92 percent of true density, each of the shaped abrasive particles having a respective surface comprising a plurality of sides and at least four vertices, and the shaped abrasive particles conforming to a predetermined nominal shape.
[009] Abrasive particles shaped in accordance with the present disclosure are useful, for example, in the manufacture of abrasive articles (e.g. coated abrasives, bonded abrasives, abrasive brushes, and/or non-woven abrasives).
[010] Consequently, in yet another aspect, the present disclosure provides an abrasive article comprising shaped abrasive particles retained in a binder, the shaped abrasive particles comprising alpha alumina, the alpha alumina having an average crystal grain size 0.8 to 8 microns, the alpha alumina having a bulk density that is at least 92 percent of the true density, and the shaped abrasive particles conforming to a predetermined nominal shape.
[011] Abrasive particles and abrasive articles according to the present disclosure are useful, for example, for abrading a workpiece.
[012] In yet another aspect, the present disclosure provides a method of abrading a workpiece, the method comprising contacting at least one shaped abrasive particle contained in an abrasive article in accordance with the present disclosure with a workpiece. of work, and moving at least one abrasive article or workpiece relative to the other to abrade at least a portion of the workpiece.
[013] As used herein: the term “apparent density” refers to the mass of a material divided by its apparent volume (ie, the volume including the internal void space); the term "colloidal" refers to a system in which finely divided particles, which are about 10 to 10,000 angstroms in size, are dispersed within a continuous liquid medium in a manner that prevents them from being easily filtered or rapidly decanted. ; the term "crystal grain" refers to a single crystal in a single crystal or monocrystalline material in which the crystal lattice of the single crystal is continuous and uninterrupted at its edges, without inner grain boundaries; the term “grain contour” refers to a defect in the crystal structure of a crystal grain forming an interface between two crystal grains, or crystallites, in a polycrystalline material; the term “mesh” used in reference to particle size refers to US mesh size, unless otherwise indicated; the term “non-colloidal” means not having the characteristics of a colloid. the term “co-formed” means that the shape is a result of intentionally formatting to a predetermined shape during manufacturing; the term “smooth” in reference to a surface means that the surface is free from irregularities, roughness, or projections, except as may be caused by irregularities caused by the manufacturing process used to make them; the term “true density” refers to the density of a given material, excluding any interior void volume in the material, determined at a given pressure and temperature (eg pressure of one atmosphere and a temperature of 25°C). the phrase "wherein the shaped abrasive particles conform to a predetermined nominal shape" means that the shapes of the shaped abrasive particles substantially correspond to an intended (predetermined) nominal shape determined by the method in which they were produced (e.g., by molding, extrusion or screen printing), allowing shrinkage during drying, calcining and sintering, and random deviations (eg, minor defects or warps) that can occur due to process variability.
[014] Advantageously, the abrasive particles shaped according to the present disclosure can exhibit excellent abrasive characteristics when incorporated into coated, bonded and/or non-woven abrasives, for example, in the form of discs and/or mats. Additionally, the grinding characteristics of the shaped abrasive particles are substantially maintained, even when the alumina microstructure within the shaped abrasive particles (i.e., crystal grain size) thickens significantly above the range of about 1-2 microns (one level of crystal grain size which is generally accepted in the art as borderline, useful for precision grinding and coated abrasive applications). This contrasts with the commercially available sol-gel-derived shaped abrasive microstructure of alumina particles.
[015] Advantageously, abrasive particles, in accordance with the present disclosure, can be produced using less expensive starting materials than would be used in a typical sol-gel process, achieving substantially equivalent abrasion performance (or better).
[016] The features and advantages of the present disclosure will be better understood in light of the detailed disclosure as well as the appended claims. Brief revelation of drawings
[017] Figure 1 is a schematic perspective view of an exemplary shaped abrasive particle 100 according to the present disclosure.
[018] Figure 2 is a schematic side view of an exemplary coated abrasive article 200 in accordance with the present disclosure.
[019] Figure 3 is a schematic side view of another exemplary coated abrasive article 300 according to the present disclosure.
[020] Figure 4 is a schematic perspective view of an exemplary grinding wheel 400 in accordance with the present disclosure.
[021] Figure 5 is a schematic representation, magnified about 100x, of an exemplary non-woven abrasive article 500 in accordance with the present disclosure.
[022] Figure 6 is a scanning electron microscope (SEM) microscopy of a shaped abrasive particle fracture surface from Example 5.
[023] Figure 7 is a microscopy (SEM) of a corner of the shaped abrasive grain of Example 6 heated to 1550°C.
[024] Figure 8 is a microscopy (SEM) of an edge of the shaped abrasive grain of Example 6 heated to 1575°C.
[025] Figure 9 is a microscopy (SEM) of a shaped abrasive particle fracture surface from Example 8c.
[026] Figure 10 is a microscopy (SEM) of a shaped abrasive particle fracture surface from Example 8e.
[027] Although the figures identified above demonstrate various modalities of the present disclosure, other modalities are also contemplated; for example, as noted in the discussion. In all cases, disclosure is presented through representation and not limitation. It should be understood that those skilled in the art may contemplate various other modifications and modalities that are included within the character and scope of the principles of the present disclosure. Figures may not be drawn to scale. Similar reference numbers may be used in all figures to denote similar parts. Detailed Description
[028] The shaped abrasive particles according to the present disclosure can be produced according to a multi-step process using a slurry comprising non-colloidal solid particles and a liquid carrier. Typically, non-colloidal solid particles are suspended in the liquid vehicle; however, it is also acceptable to have some settling of the non-colloidal solid particles. At least some of the non-colloidal solid particles comprise at least one of alpha alumina or a precursor thereof. In some embodiments, the solid non-colloidal particles comprise alpha alumina particles, alpha alumina precursor particles, or a combination thereof. In some embodiments, substantially all (e.g., at least 95 percent by weight, or at least 99 percent by weight), or all, of the non-colloidal solid particles comprise alpha alumina particles, alpha alumina precursor particles, or a combination of them.
[029] Alpha alumina particles and non-colloidal alpha alumina precursor particles, taken individually, or collectively if both are present, may comprise at least 30, 35, 40, 50, or even at least 55 percent by volume of the slurry. The slurry may further comprise one or more optional additives such as, for example, thixotrope(s), dispersant(s), wetting agent(s), defoamer(s), agent(s) ) coupling agent(s), modifying agent(s) or precursor(s) thereof, nucleating agent(s), peptizing agent(s), and/or template release agent(s). Useful thickeners include: organic thickener(s) such as, for example, guar gum, sodium carboxymethyl cellulose, and/or carbomers; and inorganic thickeners such as colloidal boehmite.
[030]The modification additives can work to improve some desirable property of the abrasive particles or increase the effectiveness of the subsequent sintering step. The precursors or modification additives of the modification additives may be in the form of micron-scale and sub-micron-scale particulates, nano-colloids (ie, nanometer-scale colloids), soluble salts, typically water-soluble salts and non-soluble salts . They typically consist of a metal-containing compound and can be a precursor of magnesium oxide, zinc, iron, silicon, cobalt, nickel, zirconium, hafnium, chromium, yttrium, praseodymium, samarium, ytterbium, neodymium, lanthanum, gadolinium, cerium, dysprosium, erbium, titanium and mixtures thereof. Determining the specific level of these additives is within the ability of a person skilled in the art.
[031] Suitable nucleating agents for inclusion in the slurry may include, for example, fine particles of alpha alumina, alpha ferric oxide or its precursor, titanium oxides and titanates, chromium oxides or any other material that will nucleate the transformation . The amount of nucleating agent, if used, should be sufficient to effect alpha alumina transformation. The nucleation of such alpha alumina precursor dispersions is disclosed in US Patent No. 4,744,802 (Schwabel).
[032]If a colloidal boehmite thickener is included in the slurry, a pelletizing agent may be useful to provide stability. Suitable peptizing agents include monoprotic acids or acid compounds such as acetic acid, hydrochloric acid, formic acid and nitric acid. Multiprotic acids can also be used, but they can quickly gel the slurry, making it difficult to handle or introduce additional components into it.
[033] In some embodiments, the solid non-colloidal particles comprise alpha alumina particles. Alpha alumina particles can be, for example, crushed or shaped. As used herein, the term "alpha alumina particle" refers to a particle comprising alpha alumina. In some embodiments, the alpha alumina particles comprise at least 95 percent by weight or at least 99 percent by weight alpha alumina. In some embodiments, the alpha alumina particles consist of alpha alumina. Usefully, alpha alumina particles can contain metal ions other than aluminum ions (eg, Fe3+ ions). Examples of suitable alpha aluminas include alumina fused to white alpha alumina, and brown fused alumina.
[034] In some embodiments, the solid non-colloidal particles comprise precursor particles of alpha alumina. As used herein, the term "alpha alumina precursor" refers to a material, other than alpha alumina, which can be at least partially (for example, completely) converted to alpha alumina by sufficient heating. Examples of suitable alpha alumina precursors include, boehmite (Y-AIO(OH)), diaspora (α-AlO(OH)), bayerite (ie, α-Al(OH)s), and gibbsite and their polymorphs (by eg doileita and nordstrandita).
[035]Non-colloidal solid particles can be monomodal or polymodal (eg, bimodal). For example, the non-colloidal solid particles can have a bimodal distribution with about 95 percent of the non-colloidal solid particles having a mode of about 0.7 microns and about 5 percent of the non-colloidal solid particles having a mode of about 23 microns.
[036] Advantageously, the methods and shaped abrasive particles in accordance with the present disclosure are tolerant of modest levels of sodium ions in the resulting slurry components and shaped abrasive particles, in contrast to traditional sol-gel methods in which even modest levels of sodium ions tend to remarkably degrade abrasive properties of abrasive particles containing sodium ions. For example, good abrasive properties can be obtained even when the shaped abrasive particles contain, on an equivalent basis, up to about 2.5 by weight of sodium oxide, preferably from 0.03 to 2.5 percent by weight of sodium oxide, more preferably from 0.05 to 2.5 percent by weight of sodium oxide, based on the total weight of the shaped abrasive particles. In some embodiments, the shaped abrasive particles contain, on an equivalent basis, from 0.05 to 0.5 weight percent sodium oxide, based on the total weight of the shaped abrasive particles.
[037] The liquid vehicle may comprise water and/or organic solvent. The liquid vehicle comprises water in an amount or at least 50, 60, 70, 80, 90, or even at least 95 percent by weight of the liquid vehicle. Preferably any organic solvent in the liquid vehicle is water soluble, more preferably water miscible. Examples include lower alcohols (eg, methanol, ethanol, propanol), ethers (eg, glyme, and diglyme), and lactams (eg, 2-pyrrolidone).
[038] Preferably, the alpha alumina and/or alpha alumina precursor particles included in the slurry have an average particle size in the range of 0.4 to 2.0 microns, more preferably in the range of 0.4 to 0.8 microns, although that's not a requirement. In some embodiments, bimodal, or even trimodal, particle size distributions are useful. In this case, in addition to the fine particles, significantly larger sizes may be present (for example, the average particle size of 0.7 is supplemented with some percentages of particles of 2-5 microns).
[039] At least a portion of the slurry is then brought into contact with a substrate to form shaped bodies. This can be achieved in a number of ways at least.
[040] For example, shaped bodies can also be produced by molding the aqueous slurry using a production tool (ie mold), generally according to the processes developed for sol-gel dispersions, except using the slurry , instead of a sol-gel. In this method, the slurry is propelled (eg, using a knife-type coating application device, bar-type coating application device, or doctor blade) into precisely shaped mold cavities on a main surface of the substrate, for example, as described in US Patent Application Publications Nos. 2010/0146867 A1 (Boden et al.); 2010/0151195 A1 (Culler et al.); 2010/0151196 A1 (Adefris et al.); 2009/0165394 A1 (Culler et al.); and 2010/0151201A1 (Erickson et al.). In that case, it is desirable that the shaped bodies substantially retain the shape of the mold cavities, allowing for shrinkage during drying.
[041] Suitable production tools can be, for example, a belt, a blade, a continuous mat, a coating cylinder such as a gravure cylinder, a sleeve mounted on a coating cylinder or die. In one embodiment, the production tool comprises polymeric material. Examples of suitable polymeric materials include thermoplastics such as polyesters, polycarbonates, poly(ether sulfone), poly(methyl methacrylate), polyurethanes, polyvinyl chloride, polyolefin, polystyrene, polypropylene, polyethylene or combinations thereof, or heat-cured materials. In one embodiment, the entire production tool is made of a polymeric or thermoplastic material.
[042] A polymeric or thermoplastic production tool can be replicated from a metal master tool. The master tool will have an inverse pattern to the one desired for the production tool. The master tool can be produced in the same way as the production tool. In one embodiment, the master tool is made of metal, eg nickel, and is turned by diamond. In one modality, the master tool is at least partially formed with the use of stereolithography. The polymeric blade material can be heated together with the master tool such that the polymeric material is embossed with the standard master tool by pressing both together. A polymeric or thermoplastic material can also be extruded or molded into the master tool and then pressed. The thermoplastic material is cooled to solidify and produce the production tool. If a thermoplastic production tool is used, then care must be taken not to generate excessive heat that can distort the thermoplastic production tool, limiting its life. Further information on the design and fabrication of production tools or master tools can be found in US Patent Nos. 5,152,917 (Pieper et al.); 5,435,816 (Spurgeon et al.); 5,672,097 (Hoopman et al.); 5,946,991 (Hoopman et al.); 5,975,987 (Hoopman et al.); and 6,129,540 (Hoopman et al.).
[043] A scraper bar or leveler can be used to force the slurry completely into the cavities in the production tool. The remaining portion of the slurry that does not enter a cavity can be removed from the upper surface of the production tool and recycled. In some embodiments, a small portion of the slurry may remain on the top surface of the production tool, while in other embodiments, the top surface is substantially free of scattering. The pressure applied by the scraper or leveler bar is typically less than 0.6 MPa (100 psi), less than 0.3 MPa (50 psi), or even less than 60 kPa (10 psi). In some embodiments, the slurry does not extend beyond the top surface. In these embodiments, when it is desired to have the exposed surfaces of the cavities resulting in flat faces of the abrasive shaped ceramic particles, it may be desirable to fill the cavities (for example, using a set of micronozzles) and slowly dry the slurry
[044]Access to the cavities in the production tool can be from an opening in the upper surface or the lower surface of the mold. In some cases, the cavities can extend through the entire thickness of the mold. Alternatively, the cavities may extend only a portion of the mold's thickness. In one embodiment, the upper surface is substantially parallel to the lower surface of the mold, with the cavities having a substantially uniform depth. At least one side of the mold, i.e. the side on which the cavities are formed, can remain exposed to the surrounding atmosphere during the step in which the volatile component is removed.
[045] The cavities have a specified three-dimensional shape to produce the shaped abrasive ceramic particles. The depth dimension is equal to the perpendicular distance from the top surface to the lowest point on the bottom surface. The depth of a given cavity can be uniform or it can vary along its length and/or width. The cavities of a given mold can be of the same shape or of different shapes.
[046] Alternatively, the slurry can be propelled through openings in a screen or a perforated substrate (eg by screen printing). In that case, it is desirable for the slurry to have a viscosity sufficient for the shaped bodies to substantially retain their shapes (allowing for shrinkage) during drying.
[047] In either of these methods it may be desirable to include a mold release agent in the slurry, or coat the mold release onto the mold surface, to assist in removing the formed abrasive precursor particles from the substrate, if desired . Typical mold release agents include oils such as peanut oil or mineral oil, fish oil, silicones, polytetrafluoroethylene (PTFE), zinc stearate, and graphite. In general, mold release agent such as peanut oil, in a liquid such as water or alcohol, is applied to the production tool surfaces in contact with the slurry in such a way that it is about 0.6 mg/cm2 (0.1 mg/in2) to about 20 mg/cm2 (3.0 mg/in2), or between about 0.6 mg/cm2 (0.1 mg/in2) to about 30 mg/cm2 ( 5.0 mg/in2) of the mold release agent is present when a mold release is desired.
[048] The substrate can be, for example, in the form of a blade, cylinder, mat, or mat, a mat, a sheet, a continuous mat, a coating cylinder such as a gravure cylinder, or a sleeve mounted on a coating cylinder. The substrate may comprise metal (for example, as in the case of a mat or cylinder) or an organic thickener (for example, polyethylene or polypropylene).
[049] After forming the slurry into shaped bodies, the shaped bodies are at least partially dried to provide shaped abrasive precursor particles. This can be achieved, for example, using an oven, heated printing roller, heat gun, or infrared heater. As used herein, the term "drying" refers to removing at least a portion of the liquid vehicle, which may or may not refer to removing water.
[050] Desirably, the liquid vehicle is removed at a rapid evaporation rate. In some embodiments, removal of the liquid vehicle by evaporation occurs at temperatures above the boiling point of the liquid vehicle. An upper limit for the drying temperature may depend on the material from which the mold is produced. For the polypropylene tool, the temperature should generally be less than the melting point of polypropylene, preferably less than the softening point.
[051] During drying, the slurry shrinks, which can cause the cavity walls to shrink. For example, if the cavities have flat walls, then the resulting shaped abrasive ceramic particles may tend to have at least three concave main sides. By preparing the concave cavity walls (so that the cavity volume is increased) it is possible to obtain shaped ceramic abrasive particles having at least three substantially flat main sides. The degree of concavity required, in general, depends on the solids content of the slurry.
[052] Thereafter, at least a portion of the shaped abrasive precursor particles is separated from the substrate. Typically, this can be achieved, for example, by gravity, vacuum, pressurized air, or a mechanical method, such as vibration (eg, ultrasonic vibration), bending and/or beating, however, other methods can also be used. .
[053] Once separated from the substrate, at least a portion of the shaped abrasive precursor particles is converted to shaped abrasive particles.
[054] The shaped abrasive precursor particles can be additionally dried on the outside once separated from the substrate. If the slurry is dried to the desired level in the mold, this additional drying step is not necessary. However, in some cases it may be more economical to employ this additional drying step in order to minimize the time the slurry remains in the mold. Typically, shaped abrasive precursor particles will be dried for 10 to 480 minutes, or for 120 to 400 minutes, at a temperature of 50°C to 160°C, or at 120°C to 150°C.
[055] Optionally but preferably, the shaped abrasive precursor particles are then calcined. During calcination, essentially all the volatile material is removed and the various components that are present in the slurry are transformed into metal oxides. Shaped abrasive precursor particles are generally heated to a temperature of 400°C to 800°C, and maintained within this temperature range until free water and more than 90 percent by weight of any bound volatile material are removed. . In a further step, it may be desirable to introduce the modifying additive via an impregnation process. A water-soluble salt can be introduced by impregnation into the pores of the calcined shaped precursor abrasive particles. Then, the precursor shaped abrasive particles are again preheated. This option is further described in US Patent No. 5,164,348 (Wood).
[056]Whether calcined or not, the shaped abrasive precursor particles (or calcined shaped abrasive precursor particles) are sintered to form shaped abrasive particles comprising alpha alumina. Shaped abrasive particles are typically ceramic after sintering. Prior to sintering, the shaped abrasive precursor particles (optionally calcined) are not completely densified and therefore do not have the hardness desired to be used as ceramic shaped abrasive particles. Sintering typically occurs by heating the shaped (optionally calcined) abrasive precursor particles to a temperature of 1000°C to 1650°C. The heating time required to achieve densification depends on several factors, but times from five seconds to 48 hours are typical.
[057] In another modality, the duration for the sintering step is in the range of one minute to 90 minutes. After sintering, the formed abrasive ceramic particles can have a Vickers hardness of 10 GPa (gigaPascal), 16 GPa, 18 GPa, 20 GPa or greater.
[058]Other steps can be used to modify the described process such as, for example, rapidly heating the material from the calcining temperature to the sintering temperature or, centrifuging the slurry to remove sediment and/or residue. Additionally, the process can be modified by combining two or more process steps, if desired. Conventional process steps that can be used to modify the process of this disclosure are more fully described in U.S. Patent No. 4,314,827 (Leitheiser).
[059] The shaped abrasive particles prepared in accordance with the present disclosure comprise alpha alumina having an average crystal grain size of 0.8 to 8 microns (preferably 0.8 to 6 microns, and more preferably 0.8 microns at 5 microns), and a bulk density that is at least 92, 93, 94, 95, 96, 97, 98, or even at least 99 percent of the true density (eg, true density = 3.97 g/cm3 at 25°C for alpha alumina).
[060] Abrasive particles shaped in accordance with the present disclosure can be used in a wide range of particle sizes, typically ranging in size from about 10,000 microns; Preferably from about 100 to about 10,000 microns, more preferably from about 500 to about 10,000 microns, although this is not a requirement. In some embodiments, the shaped abrasive particles have an average particle size of at least 20 US mesh (i.e., > about 840 microns). Abrasive particles formed in accordance with the present disclosure may be selected and classified using techniques well known in the art, including the use of recognized abrasive industry classification standards such as ANSI (American National Standard Institute - American National Institute of Standards), FEPA (Federation of European Producers of Abrasives), and JIS (Japanese Industrial Standard). ANSI classification designations include: ANSI 4, ANSI 6, ANSI 8, ANSI 16, ANSI 24, ANSI 36, ANSI 40, ANSI 50, ANSI 60, ANSI 80, ANSI 100, ANSI 120, ANSI 150, ANSI 180, ANSI 220, ANSI 240, ANSI 280, ANSI 320, ANSI 360, ANSI 400, and ANSI 600. FEPA rating designations include P8, P12, P16, P24, P36, P40, P50, P60, P80, P100, P120, P150 , P180, P220, P320, P400, P500, P600, P800, P1000 and P1200. JIS classification designations include JIS8, JIS12, JIS16, JIS24, JIS36, JIS46, JIS54, JIS60, JIS80, JIS100, JIS150, JIS180, JIS220, JIS240, JIS280, JIS320, JIS360, JIS400, JIS400, JIS600, JIS800, JIS1000, JIS1500, JIS2500, JIS4000, JIS6000, JIS8000, and JIS10,000.
[061] Abrasive particles formed in accordance with the present disclosure have non-random shapes, generally imparted by the method used to form them. For example, shaped abrasive particles can be shaped like pyramids, truncated pyramids, rods, or cones. In some embodiments, the shaped abrasive particles have an outer surface that comprises a plurality of side walls that form at least four corners. Sidewalls are typically substantially smooth or smooth, although this is not a requirement.
[062] In some embodiments, each of the shaped abrasive particles may comprise a lower surface that adjoins a plurality of side walls, the lower surface comprising at least three vertices.
[063] In some embodiments, each of the shaped abrasive particles may further comprise a respective upper surface that is adjacent to the plurality of side walls, with the upper surface and the lower surface not in contact with each other. In some embodiments, the sidewalls taper inward from the bottom surface.
[064] Referring now to Figure 1, the exemplary shaped abrasive particle 100 in accordance with the present disclosure comprises a truncated trigonal pyramid with vertices 110, side walls 120, edges 130, bottom surface 140, and top surface 150 (non-entering in contact with the bottom surface 140). Sidewalls 120 taper inwardly from bottom surface 140. Adjacent sidewalls contact each other at one end 130 and at least two vertices 110.
[065] In another aspect, the present disclosure provides abrasive articles (for example, coated abrasive articles, bonded abrasive articles (including glazed, resinoids, and metal bonded wheels, cutting wheels, mounted tips, and emery stones), abrasive non-woven articles, and abrasive brushes) comprising a binder and abrasive particles shaped in accordance with the present disclosure retained in the binder. Methods of preparing such abrasive articles and using the abrasive articles are well known to those skilled in the art. Additionally, abrasive particles shaped in accordance with the present disclosure can be used in abrasive applications, which utilize abrasive particles, such as slurries of abrasive compounds (e.g., polishing compounds), grinding media, blasting media, grinding media, vibrating mills, and the like.
[066] Coated abrasive articles generally include a support, abrasive particles, and at least one binder for hanging the abrasive particles onto the support. Examples of suitable carrier materials include woven cloth, polymeric film, vulcanized fiber, a non-woven fabric, a knitted fabric, paper, combinations thereof, and treated versions thereof. The binder can be any suitable binder, including an inorganic or organic binder (including heat curable resins and radiation curable resins). Abrasive particles can be present in one layer or two layers of the coated abrasive article.
[067] An exemplary embodiment of a coated abrasive article in accordance with the present disclosure is shown in Figure 2. Referring to Figure 2, the coated abrasive article 200 has a backing 220 and abrasive layer 230. The abrasive layer abrasive layer 230 includes shaped abrasive particles 240 in accordance with the present disclosure secured to main surface 270 of support 220 (substrate) by base coat 250 and size coat 260. Shaped abrasive particles 240 contact base coat 250. Size coat 260 is disposed on at least a portion of the base coat 250 and at least a portion of the shaped abrasive particles 240. The base coat 250 and the size coat 260 each comprise a respective binder which may be the same or different.
[068] Another exemplary coated abrasive article in accordance with the present disclosure is shown in Figure 3. Referring to Figure 3, the exemplary coated abrasive article 300 has a backing 320 (substrate) and structured abrasive layer 330. The structured abrasive layer 330 includes a plurality of abrasive composites 335 comprising shaped abrasive particles 340 in accordance with the present disclosure dispersed in a binder 350 secured to a main surface 370 of support 320.
[069] Abrasive articles coated in accordance with the present disclosure may include additional layers, such as an optional oversized layer that is superimposed on the abrasive layer, or a layer and/or antistatic treatment may also be disposed over the opposite support of the abrasive layer, if desired.
[070] Details relating to coated abrasive articles and methods for their fabrication can be found, for example, in US Patent Nos. 4,734,104 (Broberg); 4,737,163 (Larkey); 5,203,884 (Buchanan et al.); 5,152,917 (Pieper et al.); 5,378,251 (Culler et al.); 5,436,063 (Follett et al.); 5,496,386 (Broberg et al.); 5,609,706 (Benedict et al.); 5,520,711 (Helmin); 5,961,674 (Gagliardi et al.), and 5,975,988 (Christianson).
[071] Bonded abrasive articles typically include a shaped mass of abrasive particles (comprising shaped abrasive particles in accordance with the present disclosure and optionally crushed abrasive particles) held together by an organic, metallic, or vitrified binder. This shaped mass can be, for example, in the form of a wheel, such as a grinding wheel or grinding wheel. The wheel diameter is typically about one cm to more than one meter; the diameter of the cutting wheels is from about 1 cm to more than 80 cm (more typically 3 cm to about 50 cm). The thickness of the cutting wheels is typically from about 0.5mm to about 5cm, more typically about 0.5mm to about 2cm. The shaped mass may also be in the form of, for example, a sharpening stone, a segment, a mounted point, a disk (for example a double disk crusher) or other conventional abrasive shape. Bonded abrasive articles typically comprise about 3 to 50 percent by volume of the bonding material, about 30 to 90 percent by volume of abrasive particles (or blends of abrasive particles), up to 50 percent by volume of additives (including grinding aids), and up to 70 percent pore volume, based on the total volume of the bonded abrasive article.
[072] An exemplary shape is a grinding wheel. Referring to Figure 4, grinding wheel 400 in accordance with the present disclosure includes shaped abrasive particles 440 in accordance with the present disclosure, retained by a binder 430, molded into a wheel, and mounted on the wheel hub 420.
[073]Further details regarding bonded abrasive articles can be found, for example, in US Patent no. 4,543,107 (Rue), US Patent No. 4,741,743 (Narayanan et al.), US Patent No. 4,800,685 (Haynes et al.), US Patent No. 4,898,597 (Hay et al.); 4,997,461 (Markhoff-Matheny et al.); 5,037,453 (Narayanan et al.); and US Patent No. 5,863,308 (Qi et al.).
[074] Abrasive non-woven articles typically typically include a high open porous polymer filament structure which has abrasive particles shaped in accordance with the present disclosure distributed throughout the structure and adherently bonded thereto by a binder organic. Examples of filaments include polyester fibers, polyamide fibers and polyaramid fibers. In Figure 5, a schematic representation, magnified about 100x, of an exemplary nonwoven abrasive article 500 in accordance with the present disclosure is provided. Such abrasive non-woven article according to the invention comprises a raised open non-woven fiber batt 550 (substrate), onto which the shaped abrasive particles 540 in accordance with the present disclosure are adhered by binder material 560.
[075] Details relating to abrasive non-woven articles and methods for their fabrication can be found, for example, in US Pat. 2,958,593 (Hoover et al.); 4,227,350 (Fitzer); 4,991,362 (Heyer et al.); 5,712,210 (Windisch et al.); 5,591,239 (Edblom et al.); 5,681,361 (Sanders); 5,858,140 (Berger et al.); 5,928,070 (Lux); and US Patent No. 6,017,831 (Beardsley et al.).
[076] Details relating to methods and abrasive brushes for their manufacture can be found, for example, abrasive brushes include those having a plurality of unitary bristles with a support (see, for example, US Patent Nos. 5,443,906 ( Pihl et al.), 5,679,067 (Johnson et al.) and 5,903,951 (Ionta et al.) Preferably, such brushes are produced by injection molding a mixture of polymer and abrasive particles.
[077]Suitable binders (ie binder materials) include organic binders such as heat-hardened organic binders. Examples of suitable heat-hardened organic binders include phenolic resins, urea-formaldehyde resins, melamine-formaldehyde resins, urethane resins, acrylate resins, polyester resins, aminoplast resins having pendant alpha, beta-carbonyl unsaturated groups, resins. epoxy, acrylated urethane, acrylated epoxies and combinations thereof. The binder and/or abrasive article can also include additives such as fibers, lubricants, wetting agents, thixotropic materials, surfactants, pigments, dyes, antistatic agents (eg, carbon black, vanadium oxide, or graphite), coupling agents (for example, silanes, titanates or zircoaluminates), plasticizers, suspending agents, and the like. The amounts of these optional additives are selected to provide the preferred properties. Coupling agents can optimize adhesion to abrasive particles and/or filler. Binder chemistry can be thermally cured, radiation cured, or combinations thereof. Additional details on binder chemistry can be found in US Patent No. 4,588,419 (Caul et al.), US Patent No. 4,751,138 (Tumey et al.), and US Patent No. 5,436,063 (Follett et al.), al.).
[078] More specifically, with regard to vitrified bonded abrasives, vitreous bonding materials, which exhibit an amorphous structure and are typically hard, are well known in the art. In some cases, the vitreous bonding material includes crystalline phases. Bonded, glazed abrasive articles produced in accordance with the present disclosure may be in the form of a wheel, whetstone, dot-mounted abrasive shape, or other conventional abrasive shape. An exemplary bonded vitrified abrasive article in accordance with the present disclosure is a grinding wheel.
[079] Examples of metal oxides that are used to form glassy bonding materials include: silica, silicates, alumina, refrigerant, calcium oxide, potassium oxide, titanium oxide, iron oxide, zinc oxide, lithium oxide, magnesia , boria, aluminum silicate, borosilicate glass, lithium aluminum silicate, combinations thereof, and the like. Typically, vitreous bonding materials can be formed from the composition that comprises from 10 to 100 percent by weight of the glass frit, although more typically the composition comprises 20 to 80 percent by weight of the glass frit, or 30 to 70 percent by weight of the glass frit. The remaining portion of the vitreous bonding materials can be a material that is not fritted. Alternatively, the vitreous bond can be derived from a composition that does not contain frit. Vitreous bonding materials are typically aged at a temperature(s) in a range from about 700°C to about 1500°C, usually in a range from about 800°C to about 1300°C, sometimes at a range of about 900°C to about 1200°C, or even in a range of about 950°C to about 1100°C. The actual temperature at which the bond is matured depends, for example, on the particular bond chemistry.
[080] In some embodiments, the vitrified bonding materials may include those comprising silica, alumina (preferably at least 10 weight percent alumina), and boria (preferably at least 10 weight percent boria). In most cases, the vitrified bonding material further comprises alkali metal oxide(s) (eg Na2O and K2O) (in some cases at least 10 percent by weight of metal oxide(s) alkali).
[081]Binder materials can also contain fillers or grinding aids, typically in the form of a particulate material. Typically, particulate materials are inorganic materials. Examples of useful fillers for this invention include: metal carbonates (eg, calcium carbonate (eg, chalk, calcite, marl, travertine, marble and limestone), calcium magnesium carbonate, sodium carbonate, magnesium carbonate ), silica (eg quartz, glass microspheres, glass bubbles and glass fibers) silicates (eg talc, clays, (montmorillonite) feldspar, mica, calcium silicate, calcium metasilicate, sodium aluminosilicate, silicate sodium) metal sulphates (eg calcium sulphate, barium sulphate, sodium sulphate, aluminum sulphate, aluminum sulphate), natural gypsum, vermiculite, wood flour, aluminum trihydrate, carbon black , metal oxides (eg calcium oxide (lime), aluminum oxide, titanium dioxide) and metal sulfites (eg calcium sulfite).
[082] In general, the addition of a grinding aid increases the useful life of the abrasive article. A grinding aid is a material that has a significant effect on physical and/or chemical abrasion processes, resulting in improved performance. Grinding aids cover a wide variety of different materials and can be inorganic or organic. Examples of chemical groups of grinding aids include waxes, organic halide compounds, halide salts and metals and their alloys. Organic halide compounds will typically decompose during abrasion and release an acid halogen or gaseous halide compound. Examples of such materials include chlorinated waxes such as tetrachloronaphthalene, pentachloronaphthalene and polyvinyl chloride. Examples of halide salts include sodium chloride, potassium cryolite, sodium cryolite, ammonium cryolite, potassium tetrafluoroborate, sodium tetrafluoroborate, silicon fluorides, potassium chloride, and magnesium chloride. Examples of metals include tin, lead, bismuth, cobalt, antimony, cadmium, iron and titanium. Other assorted grinding aids include sulfur, organic sulfur compounds, graphite and metal sulfides. A combination of different grinding aids can be used, and in some cases this can produce a synergistic effect.
[083] Grinding aids can be particularly useful in coated and bonded abrasive articles. In coated abrasive articles, the grinding aid is typically used in the oversize coating, which is applied to the surface of the abrasive particles. Sometimes, however, grinding aid is added to the sizing coating. Typically, the amount of grinding aid incorporated into coated abrasive articles is about 50 to 300 grams per square meter (g/m2), preferably about 80 to 160 g/m2 . In vitrified bonded abrasive articles, the grinding aid is typically impregnated into the pores of the article.
[084]Abrasive articles may contain 100% abrasive particles shaped in accordance with the present disclosure, or blends of such abrasive particles with other abrasive particles and/or diluent particles. Meanwhile, at least about 2 percent by weight, preferably at least about 5 percent by weight, and more preferably about 30 to 100 percent by weight, of the abrasive particles in the abrasive articles should be abrasive particles. formed in accordance with the present disclosure.
[085] In some cases, abrasive particles shaped in accordance with the present disclosure may be mixed with other abrasive particles and/or thinner particles in a ratio of between 5 and 75 percent by weight, about 25 to 75 percent by weight. weight about 40 to 60 percent by weight, or about 50 to 50 percent by weight (i.e., in equal amounts by weight).
[086] Examples of suitable conventional abrasive particles include molten aluminum oxide (including white fused alumina, heat treated aluminum oxide and brown aluminum oxide), silicon carbide, boron carbide, titanium carbide, diamond, cubic boron nitride , garnet, alumina-zirconia, and abrasive particles derived from sol-gel and the like. Conventional sol-gel derived abrasive particles can be seeded or unseeded. Similarly, they can be randomly shaped or have a shape associated with them, such as a rod or a triangle. In some cases, abrasive particle blends can result in an abrasive article that exhibits improved grinding performance compared to abrasive articles that comprise 100 percent of one or another type of abrasive particles.
[087]If there is a blend of abrasive particles, the types of abrasive particles that make up the mixture can be the same size. Alternatively, abrasive particle types can be of different particle sizes. For example, the oversized abrasive particles can be abrasive particles in accordance with the present disclosure, with the undersized particles being another type of abrasive particles. On the other hand, for example, the smaller sized abrasive particles may be abrasive particles in accordance with the present disclosure, with the larger sized particles being another type of abrasive particle.
[088] Examples of suitable diluent particles include marble, plaster, stone, silica, iron oxide, aluminum silicates, glass (including glass bubbles and glass microspheres), alumina bubbles, alumina microspheres, and thinner agglomerates.
[089] Abrasive particles shaped in accordance with the present disclosure may also be combined into, or with, abrasive agglomerates. Abrasive agglomerate particles typically comprise a plurality of abrasive particles, a binder, and optional additives. The binder can be organic and/or inorganic. Abrasive agglomerates can be randomly formed or have a predetermined shape associated with them. The format can be, for example, a block, cylinder, pyramid, coin, or a square. Abrasive agglomerate particles typically have particle sizes in the range of about 100 to about 5000 microns, typically about 250 to about 2500 microns.
[090]Abrasive particles can be evenly distributed in the abrasive article or concentrated in selected areas or portions of an abrasive article. For example, in a coated abrasive, there may be two layers of abrasive particles. The first layer comprises abrasive particles in addition to abrasive particles shaped in accordance with the present disclosure, and the second (outermost) layer comprises abrasive particles shaped in accordance with the present disclosure. Similarly in an abrasive, there may be two distinct sections of the grinding wheel. The outermost section may comprise abrasive particles shaped in accordance with the present disclosure, while the innermost section does not. Alternatively, the abrasive particles shaped in accordance with the present disclosure may be evenly distributed throughout the abrasive article.
[091] The present disclosure provides a method of abrading a workpiece. The method comprises: frictionally contacting the abrasive particles in accordance with the present disclosure with a surface of the workpiece, and moving at least one of the abrasive particles and the surface of the workpiece relative to the other to abrade on at least a portion of the surface of the part. Methods for abrading with abrasive particles in accordance with the present disclosure include, for example, dredging (i.e., removal of stock solution at high pressure) to polishing (e.g., polishing of medical implants with coated abrasive mats) in the latter is typically made with finer grades (eg ANSI 220 and finer) of abrasive particles. Abrasive particles can also be used in precision abrasion applications such as grinding camshafts with glazed bonded wheels. The size of the abrasive particles used to abrade a specific application will be apparent to those skilled in the art.
[092]Abrasion can be performed dry or wet. For wet abrasion, the liquid provided can be introduced as a light mist to complete the soak. Examples of commonly used liquids include: water, water-soluble oil, organic lubricant, and emulsions. The liquid can serve to reduce the associated heat of abrasion and/or act as a lubricant. The liquid may contain minor amounts of additives such as bactericides, defoamers, and the like.
[093] Examples of workpieces include aluminum metal, carbon steels, mild steels (eg 1018 mild steel and 1045 mild steel), tool steels, stainless steel, hardened steel, titanium, glass, ceramics, wood, materials wood-like (eg plywood and particle board), paint, painted surfaces, organic coated surfaces, and the like. The force applied during abrasion typically ranges from about 1 to about 100 kilograms (kg), although other pressures can also be used. Selected modalities of this disclosure
[094] In a first embodiment, the present disclosure provides a method of preparing abrasive particles, the method comprising: providing a slurry comprising non-colloidal solid particles and a liquid carrier, at least some of the non-colloidal solid particles comprising at least at least one of alpha alumina or an alpha alumina precursor, and the non-colloidal solid particles comprising at least 30 percent by volume of the slurry; forming at least a portion of the slurry into shaped bodies which come into contact with a substrate, the shaped bodies being formed substantially in accordance with a predetermined shape; at least partially drying the shaped bodies to provide shaped abrasive precursor particles; separating at least a portion of the shaped abrasive precursor particles from the substrate; and converting at least a portion of the shaped abrasive precursor particles to shaped abrasive particles, the shaped abrasive particles comprising alpha alumina, the alpha alumina having an average crystal grain size of 0.8 to 8 microns and a bulk density which is at least 92 percent of the true density, and wherein each of the shaped abrasive particles has a respective surface comprising a plurality of sides and at least four vertices.
[095] In a second embodiment, the present disclosure provides a method according to the first embodiment, wherein the substrate has cavities on the surface thereof, and said slurry formation in shaped abrasive precursor particles that enter into contacting the substrate comprise pushing the slurry into at least a portion of the cavities.
[096] In a third embodiment, the present disclosure provides a method according to the first or second embodiment, wherein said slurry conformation comprises pushing the slurry through a screen onto the substrate.
[097] In a fourth embodiment, the present disclosure provides a method according to any of the first to third embodiments, wherein the non-colloidal alpha alumina precursor particles contain, on an equivalent basis, at least 0.03 percent in weight of sodium oxide, based on the total weight of shaped abrasive precursor particles.
[098] In a fifth embodiment, the present disclosure provides a method according to any of the first to fourth embodiments, said conversion of at least a portion of the shaped abrasive precursor particles into the shaped abrasive particles comprises: sintering the precursor particles shaped abrasives to supply the shaped abrasive particles.
[099] In a sixth embodiment, the present disclosure provides a method according to any one of the first to fourth embodiments, said conversion of at least a portion of the shaped abrasive precursor particles into the shaped abrasive particles comprises: calcining the precursor particles shaped abrasives to provide calcined shaped abrasive precursor particles; and sintering the calcined precursor abrasive particles to provide the shaped abrasive particles.
[0100] In a seventh embodiment, the present disclosure provides a method according to any one of the first to sixth embodiments, said conversion of at least a portion of the shaped abrasive precursor particles into the shaped abrasive particles comprises: impregnating the precursor particles shaped abrasives with a metal salt solution to provide impregnated shaped abrasive precursor particles; and sintering the impregnated shaped abrasive precursor particles to provide the shaped abrasive particles.
[0101] In an eighth embodiment, the present disclosure provides a method according to any one of the first to sixth embodiments, said conversion of at least a portion of the shaped abrasive precursor particles into the shaped abrasive particles comprises: calcining the precursor particles shaped abrasives to provide calcined shaped abrasive precursor particles; impregnating the calcined precursor abrasive particles with a metal salt solution to provide impregnated calcined precursor abrasive particles; and sintering the impregnated calcined precursor abrasive particles to provide the shaped abrasive particles.
[0102] In a ninth embodiment, the present disclosure provides a method according to any one of the first to eighth embodiments, wherein the non-colloidal alpha alumina precursor particles comprise powdered aluminum oxide.
[0103] In a tenth embodiment, the present disclosure provides a method according to any one of the first to ninth embodiments, wherein the non-colloidal alpha alumina precursor particles comprise ground aluminum trihydrate particles.
[0104] In an eleventh embodiment, the present disclosure provides a method according to any one of the first to tenth embodiments, wherein the non-colloidal alpha alumina precursor particles contain, on an equivalent basis, 0.03 to 0.25 percent sodium oxide based on the total weight of shaped abrasive precursor particles.
[0105] In a twelfth embodiment, the present disclosure provides a method according to any one of the first to eleventh embodiments, wherein the non-colloidal alpha alumina precursor particles have an average particle diameter of at least 0.2 microns .
[0106] In a thirteenth embodiment, the present disclosure provides a method according to any one of the first to the twelfth embodiments, the slurry further comprising a thickener.
[0107] In a fourteenth modality, the present disclosure provides a method according to a twelfth modality, wherein the thickener comprises colloidal boehmite.
[0108] In a fifteenth embodiment, the present disclosure provides a method according to a twelfth embodiment, wherein the thickener comprises an organic thickener.
[0109] In a sixteenth embodiment, the present disclosure provides a method according to any one of the first to fifteenth embodiments, wherein the shaped abrasive particles have an average particle size greater than 20 mesh.
[0110] In a seventeenth embodiment, the present disclosure provides a method according to any one of the first to sixteenth embodiments, wherein the non-colloidal alpha alumina precursor particles comprise at least 40 percent by volume of the slurry.
[0111] In an eighteenth embodiment, the present disclosure provides shaped abrasive particles produced according to a method of any one of the first through seventeenth embodiments.
[0112] In a nineteenth modality, the present disclosure provides an abrasive article comprising abrasive particles shaped according to the eighteenth modality, retained in a binder, the shaped abrasive particles comprising alpha alumina, with alpha alumina having a average crystal grain size of 0.8 to 8 microns, alpha alumina having a bulk density that is at least 92 percent of true density, and the shaped abrasive particles conforming to a predetermined nominal shape.
[0113] In a twentieth modality, the present disclosure provides an abrasive article according to the nineteenth modality, and the abrasive article further comprises: a support; a base coat attached to a main surface of the support, the shaped abrasive particles contacting the base coat; and a size coat disposed over at least a portion of the base coat and at least a portion of the shaped abrasive particles.
[0114] In a twenty-first embodiment, the present disclosure provides an abrasive article comprising abrasive particles shaped according to the nineteenth to twentieth embodiments, the abrasive article further comprising a support and an abrasive layer in contact with a main surface of the support, the abrasive layer comprising the binder and the shaped abrasive particles.
[0115] In a twenty-second embodiment, the present disclosure provides an abrasive article comprising abrasive particles shaped according to the nineteenth embodiment, the abrasive article, the abrasive article further comprising a high open fiber mat.
[0116] In a twenty-third embodiment, the present disclosure provides an abrasive article comprising abrasive particles shaped according to the nineteenth embodiment, wherein the abrasive article comprises an attached abrasive wheel.
[0117] In a twenty-fourth embodiment, the present disclosure provides a method of abrading a workpiece, the method comprising contacting at least one shaped abrasive particle contained in an abrasive article of any one of the nineteenth to twenty-third arrangements with a workpiece, and moving at least one abrasive article or workpiece relative to the other to abrade at least a portion of the workpiece.
[0118] In a twenty-fifth modality, the present disclosure provides shaped abrasive particles comprising alpha alumina, with alpha alumina having an average crystal grain size of 0.8 to 8 microns, with alpha alumina having a bulk density which is at least 92 percent of true density, each of the shaped abrasive particles having a respective surface comprising a plurality of sides and at least four vertices, and the shaped abrasive particles conforming to a predetermined nominal shape.
[0119] In a twenty-sixth modality, the present disclosure provides abrasive particles shaped according to the twenty-fifth modality, each respective surface further comprising at least four edges, with the average width of each edge ranging from about 5 to 20 microns and the ratio of average width of each edge to average crystal grain size is in a range of 1 to 25.
[0120] In a twenty-seventh modality, the present disclosure provides abrasive particles shaped in accordance with the twenty-fifth or twenty-sixth modality, each of the shaped abrasive particles respectively comprising the lower surface adjoining a plurality of side walls, wherein the lower surface comprises at least three vertices.
[0121] In a twenty-eighth modality, the present disclosure provides shaped abrasive particles according to the twenty-seventh modality, each of the shaped abrasive particles further comprising a respective upper surface that is contiguous with the plurality of side walls , where the upper surface and the lower surface do not come into contact with each other.
[0122] In a twenty-ninth modality, the present disclosure provides abrasive particles shaped according to the twenty-seventh or twenty-eighth modality, with the side walls tapering inward from the bottom surface.
[0123] In a thirtieth embodiment, the present disclosure provides shaped abrasive particles according to any one of the twenty-fifth to twenty-ninth embodiments, wherein the shaped abrasive particles contain on an equivalent basis at least 0.03 percent by weight of oxide of sodium, based on the total weight of the shaped abrasive particles.
[0124] In a thirty-first modality, the present disclosure provides shaped abrasive particles according to any one of the twenty-fifth to twenty-ninth modalities, wherein the shaped abrasive particles contain 0.03 to 0.25 percent sodium oxide with based on the total weight of the formed abrasive particles.
[0125] In a thirty-second embodiment, the present disclosure provides shaped abrasive particles according to any one of the twenty-fifth to thirty-first embodiments, wherein the shaped abrasive particles have an average particle size that matches a US mesh size in the range from 6 to 80.
[0126] In a thirty-third embodiment, the present disclosure provides an abrasive article comprising shaped abrasive particles retained in a binder, the shaped abrasive particles comprising alpha alumina, the alpha alumina having an average crystal grain size of 0 .8 to 8 microns, the alpha alumina having a bulk density that is at least 92 percent of the true density, and the shaped abrasive particles conforming to a predetermined nominal shape.
[0127] In a thirty-fourth modality, the present disclosure provides an abrasive article according to the thirty-third modality, the abrasive article further comprising: a support; a base coat attached to a main surface of the support, the shaped abrasive particles contacting the base coat; and a size coat disposed over at least a portion of the base coat and at least a portion of the shaped abrasive particles.
[0128] In a thirty-fifth modality, the present disclosure provides an abrasive article according to the thirty-third modality, the abrasive article further comprising a support and an abrasive layer in contact with a main surface of the support, wherein the layer abrasive comprises the binder and the shaped abrasive particles.
[0129] In a thirty-sixth embodiment, the present disclosure provides an abrasive article according to the thirty-third embodiment, the abrasive article further comprising a high open fiber mat.
[0130] In a thirty-seventh embodiment, the present disclosure provides an abrasive article according to the thirty-third embodiment, wherein the abrasive article comprises an attached abrasive wheel.
[0131] In a thirty-eighth embodiment, the present disclosure provides a method of abrading a workpiece, the method comprising contacting an abrasive article according to any one of the thirty-third to thirty-seventh embodiments with the workpiece, and moving at least one abrasive article or workpiece relative to the other to abrade at least a portion of the workpiece.
[0132] The objectives and advantages of this disclosure are further illustrated by the following non-limiting examples, but the specific materials and proportions thereof mentioned in these examples, as well as other conditions and details, should not be construed as unduly limiting this disclosure. Examples
[0133] Except where otherwise specified, all parts, percentages, ratios, etc. in the Examples they are expressed by weight. Examples 1-7
[0134] A polyethylene lined ball mill vessel was loaded with 100 grams (g) of deionized water, 0.5 g of ammonium citrate dispersing agent, 400 g of different powdered aluminum oxides (as reported in Table 1, with raw material sources reported in Table 2). About 700 grams of alumina milling medium (10 mm diameter; 99.9% alumina; obtained from Union Process, Akron, Ohio, USA) was added to the tube, and the mixture was milled at 120 rpm for 24 hours. After milling, the milling medium was removed and the slurry was degassed by placing it in a desiccator bottle and applying a vacuum, using a mechanical pump (about 10 minutes kept under vacuum). The resulting slurry was poured onto a polyethylene sheet containing a replicated pattern of triangular truncated pyramids about 0.4 mm in side length, 0.1 mm in depth, having a topical coating of mineral oil deposited by drying a solution of 5 percent by weight ethanol. The slurry was spread to cover an approximate 400 cm2 area of the slide using a squeegee. The slide containing the ceramic slurry was then dried under a heat gun. After drying the blade was shaken vigorously to dislodge the resulting shaped abrasive precursor particles which were now in the form of truncated triangular pyramids.
[0135] The shaped abrasive precursor particles were calcined by placing them in an alumina crucible and heating to 700°C (heating rate 10°C/min) in air. No maintained isotherms were applied. The particles remained pyramids after this step and were strong enough to withstand further manipulation.
[0136] About 300 g of the calcined shaped abrasive precursor particles were placed in an alumina crucible and sintered in an electrically heated oven Model KKSK-666-3100 available from Keith Furnaces of Pico Rivera, California, USA, using a heating rate of 25°C/min and a retention time of 45 min at the final temperature which is shown in Table 1.
[0137]The resulting sintered shaped abrasive particle densities were measured using an ACCUPYC II 1330 pycnometer available from Micromeritics Instrument Corporation, Norcross, Georgia, USA, according to standard operating procedure. The results are documented in Table 1.
[0138]The average crystal size was determined by the in-line interception method according to the ASTM E112-96 test method “Standard Test Methods for Determining Average Grain Size”. Approximately 5 g of the shaped abrasive particles were placed in a plastic bag and crushed with a hammer to generate fractured particles. The resulting mixture of fractured and unfractured shaped abrasive particles was mounted on a platform, coated with a thin layer of gold-palladium, and visualized using a JEOL Model 7600F Scanning Electron Microscope (SEM). A microscopy (SEM) typical of the microstructure found in the sample was used to determine the average crystal size as follows (for example, see Figure 6 which shows a microscopy (SEM) of a shaped abrasive particle fracture surface from Example 5). The number of intersecting crystals per unit length (NL) of a random line that were traced through microscopy was counted. The average crystal size was determined from this number using the following equation:
where NL is the number of intersected crystals per unit length and M is the magnification of the micrograph. The average size of the crystals in the sample is reported in Table 1 below. It's beautiful 1

Crushing performance of examples 1 -7 and comparative examples A-C
[0139]About 17 grams of the resulting shaped abrasive particles were incorporated into a coated abrasive disc. The coated abrasive wheel was produced according to conventional procedures. The shaped abrasive particles were bonded onto vulcanized fiber supports 17.8 cm in diameter, 0.8 mm thick (having a central hole 2.2 cm in diameter), using a phenolic resin filled with carbonated carbonate. conventional calcium (48% resolic phenolic resin, 52% calcium carbonate, diluted to 81% solids with water and glycol ether) and a phenolic sizing resin filled with conventional cryolite (32% resolic phenolic resin, 2% iron oxide, 66% cryolite, diluted to 78% solids with water and glycol ether). The wet base resin weight was about 185 g/m2. Immediately after the base coat was applied, the shaped abrasive particles were electrostatically coated. The base resin was heated for 120 minutes at 88°C. Then, the cryolite filled phenolic sizing coating was coated over the base coat and abrasive particles. The wet sizing weight was about 850 g/m2. The sizing resin was heated for 12 hours at 99°C. The coated abrasive wheel was flexed prior to testing.
[0140] The coated abrasive wheels of Comparative Example A were prepared as described for Example 1 (above), except heat treated fused alumina abrasive particles (obtained as ALODUR BFRPL, grade 36 available from Treibacher, Villach, Austria were used in place of the shaped abrasive particles from Example 1.
[0141] The coated abrasive discs of Comparative Example B were prepared as described for Example 6 (above), except that 36-grade alumina-zirconia abrasive particles (having an eutectic composition of 60% Al2O3 and 39% ZrO2; obtained as NORZON available from Norton Company, Worcester, Massachusetts, USA) were used in place of the shaped abrasive particles of Example 1.
[0142] The coated abrasive wheels of Comparative Example C were prepared as described above, except conventionally ground sol-gel derived abrasive particles (marketed as 3M CERAMIC ABRASIVE GRAIN 321 available from the 3M Company, St. Paul, Minnesota, USA) were used in place of the shaped abrasive particles from Example 1.
[0143] The coated abrasive discs of Comparative Example D were prepared as described above with the exception that randomly shaped abrasive particles prepared by bulk drying the slurry of the material from Example 1, sintering and grinding to provide grade 36 were used in place of the shaped abrasive particles of Example 1.
[0144] The grinding performance of the coated abrasive discs of Examples 1-7 and Comparative Examples AD was evaluated as follows. Each coated abrasive wheel was mounted on a beveled aluminum support block, and used to grind the face of a pre-weighed 1.25cm x 18cm x 10cm 1018 light steel workpiece. The wheel was driven to 5,000 revolutions per minute (rpm) while the portion of the disc that overlaps the beveled edge of the support block contacted the workpiece with a load of 8.6 kilograms. Each disk was used to grind an individual workpiece in a sequence of one minute intervals. The total cut was the sum of the amount of material removed from the workpiece over the test period. The total cuts for each sample after 12 minutes of milling are reported in Table 3 below, where an average cut of two discs is reported. Table 3

Examples 8A to 8F
[0145] The shaped abrasive particles of Examples 8a - 8e were prepared as described in Example 2, except that the procedure was repeated several times to generate a greater amount of material. The sintered shaped particles were subsequently subjected to grain growth-inducing heat treatments that included a ramp rate of 25°C/min from room temperature to the highest burn temperature (reported in Table 4). The materials of Examples 8a through 8e differ from the higher firing temperature used for heat treatment.
[0146] The material of Example 8f was prepared as described in Example 2, except the proportion of water and alumina and powder was changed to 100 g and 200 g, respectively. This change yielded a more fluid slurry that, when dried on a replicated blade, produced shaped abrasive particles with fewer sharp edges. Milling characteristics and average grain size were analyzed as described for Example 2.
[0147] The microstructural edge sharpening (EMS) was measured for all shaped abrasive particles produced in these Examples. This parameter can be obtained using an SEM observation pattern according to the following procedure. Approximately 1 gram of shaped abrasive particles was assembled in one stage, coated with a thin layer of gold-palladium, and visualized using a JEOL Model 7600F Scanning Electron Microscope (SEM). Typical SEM micrographs of shaped abrasive grain edge and corner are shown in Figures 7 and 8, respectively.
[0148]The crystal grain size of the material is obtained as described above (see also Figures 9 and 10). Referring to Figure 7, the edge width is 12.8 microns and the average crystal grain size is about 7.5 microns. EMS is defined here as the ratio of the average edge width to the average crystal grain size at the edge. Thus, the microstructural edge sharpening is about 1.7.
[0149]The EMS of the shaped abrasive particles from Example 7 is shown in Table 4, where the average of six measurements along the edge is reported. Referring to Table 4, good crushing characteristics generally correlate with higher EMS numbers unless the leading edge width is very high. Regardless of the crystal grain size, the initial edge width is defined during the processing procedure where slurry is replicated in a triangular pattern. For each of Examples 8a-8e the leading edge width was measured to be about 9.3 microns. In example 8f, however, the initial edge width was about 13.8 microns resulting in a decrease in crushing characteristics. Finally, for good crushing performance the shaped abrasive grains should have edge widths less than about 15-20 microns, preferably as low as 12, 10 or even 8 microns and the EMS parameter should be greater than 1, preferably greater than 1.5 or even 2. It looks like 4 EXEMPL

Examples 9-13
[0150]Examples 9-13 were prepared as described in Example 1, except that various sintering additives were introduced to promote densification at lower temperatures. The lowest sintering additives and firing temperature required to achieve 96% of theoretical density are summarized in Table 5 below. Table 5
Example 14
[0151] A teflon coated attrition mill vessel was charged with 250 g of deionized water, 4 g of nitric acid (70% concentration), 190 g of SH-20 aluminum hydroxide (obtained from Dadco Aluminum and Chemicals , Lausanne, Switzerland). This powder contained about 0.25% by weight of Na2O. About 700 grams of alumina milling medium (5 mm in diameter; 99.9% alumina; obtained from Union Process) was added to the vessel, and the mixture was milled at 500 rpm for 24 hours. After milling, the milling medium was removed, and 31 g of magnesium nitrate hydroxide (Mg(NO3>6H2O, available from Sigma-Aldrich Co., Saint Louis, Missouri, USA) was added to the slurry, and homogenized with the aid of an air-driven agitation configuration. The resulting slurry was poured onto a polyethylene sheet containing replicated pattern of triangular truncated pyramids about 0.4 mm side length, 0.1 mm deep, having a topical coating of mineral oil deposited from a 5% ethanol solution and spread to cover an area of approximately 400 cm2 of the blade using a squeegee.The slurry-containing blade was then dried under a heat gun. After drying, the mat was shaken vigorously to dislodge the dry shaped abrasive precursor particles, which were now in the form of truncated triangular pyramids.
[0152] The formed abrasive precursor particles were calcined by placing them in an alumina crucible and heating to 800°C (heating rate 10°C/min) in air. No maintained isotherms were applied. The particles remained pyramids after this step and were strong enough to withstand further manipulation.
[0153] About 100 g of the calcined shaped abrasive precursor particles were placed in an alumina crucible and sintered in an electrically heated oven Model KKSK-666-3100 available from Keith Furnaces using a heating rate of 25°C /min and a retention time of 45 min at the final temperature of 1500°C. Grain density and size were determined as described in Example 1, and were 97.5% and 2.87 microns, respectively. Its grinding performance was evaluated as described in Example 1. The total cut of 965 g was obtained.
[0154] Other modifications and variations of the present disclosure may be practiced by those skilled in the art without departing from the spirit and scope of the present disclosure, which is more particularly defined in the appended claims. It is understood that aspects of the various modalities may be changed in whole or in part or may be combined with other aspects of the various modalities. All references, patents or patent applications cited in the above application for patent authorization are hereby incorporated by reference in their entirety in a consistent manner. In the event of inconsistencies or contradictions between the portions of the references incorporated into that application, the information in the foregoing disclosure shall control them. The foregoing disclosure, given for the purpose of enabling one of ordinary skill in the art to practice the claimed disclosure, is not to be construed as limiting the scope of the disclosure, which is defined by the claims and all equivalents thereto.

权利要求:
Claims (12)
[0001]
1. Method of preparing abrasive particles, the method CHARACTERIZED in that it comprises: providing a slurry comprising non-colloidal solid particles and a liquid carrier, wherein at least some of the non-colloidal solid particles comprise at least one of alpha alumina or an alpha alumina precursor, and wherein the non-colloidal solid particles comprise at least 30 percent by volume of the slurry; forming at least a portion of the slurry into shaped bodies that come into contact with a substrate, wherein the shaped bodies are formed substantially in accordance with a predetermined shape; at least partially drying the shaped bodies to provide shaped abrasive precursor particles; separating at least a portion of the shaped abrasive precursor particles from the substrate; and sintering at least a portion of the shaped abrasive precursor particles into shaped abrasive particles, wherein each of the shaped abrasive particles comprises a truncated trigonal pyramid, wherein the shaped abrasive particles comprise alpha alumina, wherein the alpha alumina has an average grain size 0.8 to 8 micron crystal and a bulk density that is at least 92 percent of true density; and wherein the shaped abrasive particles contain from 0.03 to 0.25 percent sodium oxide based on the total weight of the shaped abrasive particles.
[0002]
2. Method according to claim 1, CHARACTERIZED by the fact that the non-colloidal alpha alumina precursor particles comprise powdered aluminum oxide.
[0003]
3. Method according to claim 1 or 2, CHARACTERIZED by the fact that the non-colloidal alpha alumina precursor particles comprise ground aluminum trihydrate particles.
[0004]
4. Method according to any one of claims 1 to 3, CHARACTERIZED by the fact that the non-colloidal alpha alumina precursor particles have an average particle diameter of at least 0.2 microns.
[0005]
5. Method according to any one of claims 1 to 4, CHARACTERIZED by the fact that the slurry further comprises a thickener.
[0006]
6. Method according to claim 5, CHARACTERIZED by the fact that the thickener comprises colloidal boehmite.
[0007]
7. Method according to any one of claims 1 to 6, CHARACTERIZED by the fact that the non-colloidal alpha alumina precursor particles comprise at least 40 percent by volume of the slurry.
[0008]
8. Shaped abrasive particles, CHARACTERIZED by the fact that they comprise alpha alumina, wherein the alpha alumina has an average crystal grain size of 0.8 to 8 microns, wherein the alpha alumina has a bulk density that is at least 92 percent of true density, wherein each of the shaped abrasive particles comprises a truncated trigonal pyramid, and wherein the shaped abrasive particles conform to a predetermined nominal shape, wherein the shaped abrasive particles contain from 0.03 to 0.25 percent sodium oxide based on the total weight of shaped abrasive particles.
[0009]
9. Shaped abrasive particles, according to claim 8, CHARACTERIZED by the fact that each respective surface further comprises at least four edges, where the average width of each edge varies from about 5 to 20 microns and the average width ratio from each edge to the average crystal grain size is in a range of 1 to 25.
[0010]
10. Shaped abrasive particles, according to claim 8 or 9, CHARACTERIZED by the fact that the formed abrasive particles contain from 0.03 to 0.25 percent sodium oxide based on the total weight of the formed abrasive particles.
[0011]
11. Abrasive article, CHARACTERIZED by the fact that it comprises shaped abrasive particles retained in a binder, wherein the shaped abrasive particles comprise alpha alumina, wherein the alpha alumina has an average crystal grain size of 0.8 to 8 microns, wherein the alpha alumina has a bulk density that is at least 92 percent of the true density, wherein each of the shaped abrasive particles comprises a truncated trigonal pyramid, and wherein the shaped abrasive particles conform to a predetermined nominal shape; and wherein the shaped abrasive particles contain from 0.03 to 0.25 percent sodium oxide based on the total weight of the shaped abrasive particles.
[0012]
12. A workpiece abrasion method, the method CHARACTERIZED in that it comprises contacting the abrasive article, as defined in claim 11, with the workpiece, and moving at least one of the abrasive article or the workpiece. work relative to each other to abrade at least a portion of the workpiece.

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同族专利:

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公开号 | 公开日

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CN104768710B|2017-09-22|

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EP2914402A4|2016-07-20|

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JP2021000721A|2021-01-07|

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MX2015005167A|2015-09-04|

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EP2914402A1|2015-09-09|

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KR20150081313A|2015-07-13|

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KR102146313B1|2020-08-21|

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EP2914402B1|2021-04-28|

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RU2616464C9|2018-05-21|

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PL2914402T3|2021-09-27|

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WO2014070468A1|2014-05-08|

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JP2016500581A|2016-01-14|

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US20150267097A1|2015-09-24|

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JP6960373B2|2021-11-05|

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JP2018134733A|2018-08-30|

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RU2616464C2|2017-04-17|

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CN104768710A|2015-07-08|

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BR112015009886A2|2017-07-11|

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RU2015114083A|2016-12-20|

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JP6550335B2|2019-07-24|

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US10696883B2|2020-06-30|

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US20200277522A1|2020-09-03|

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CA2888733A1|2014-05-08|

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法律状态:
2018-03-06| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2018-03-13| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2018-03-20| B06I| Publication of requirement cancelled [chapter 6.9 patent gazette]|Free format text: ANULADA A PUBLICACAO CODIGO 6.6.1 NA RPI NO 2462 DE 13/03/2018 POR TER SIDO INDEVIDA. |

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2019-10-15| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2021-04-06| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2021-06-08| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 17/10/2013, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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US201261720721P| true| 2012-10-31|2012-10-31|

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US61/720,721|2012-10-31|

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PCT/US2013/065421|WO2014070468A1|2012-10-31|2013-10-17|Shaped abrasive particles, methods of making, and abrasive articles including the same|

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